BUILDING OFF THE BACK OF CHELATORS - SYNTHESIS OF 3,3''-BIS(4-METHYLPHENYL)-2,2' 6',2''-TERPYRIDINE/

Authors
BENNISTON AC
Citation
Ac. Benniston, BUILDING OFF THE BACK OF CHELATORS - SYNTHESIS OF 3,3''-BIS(4-METHYLPHENYL)-2,2' 6',2''-TERPYRIDINE/, Tetrahedron letters, 38(47), 1997, pp. 8279-8282
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
47
Year of publication
1997
Pages
8279 - 8282
Database
ISI
SICI code
0040-4039(1997)38:47<8279:BOTBOC>2.0.ZU;2-1
Abstract
Using an adaptation of the Jameson method for the synthesis of 2,2':6' ,2''-terpyridine (terpy), a ditolyl-functionalised ligand has been pre pared in which the substituted groups are located in the highly unusua l 3,3 '' position. The new ligand represents an attempt to develop ter py-based systems with di-functionality that emerges from the 'back sid e' of the chelator. (C) 1997 Elsevier Science Ltd.