SMALL-ANGLE NEUTRON-SCATTERING STUDIES OF THE FRACTAL-LIKE NETWORK FORMED DURING DESORPTION AND ADSORPTION OF WATER IN POROUS MATERIALS

Small-angle neutron scattering (SANS) has been used to study the adsor ption and desorption behavior of a D2O/H2O water mixture in porous mat erials. When the porous solid is partially saturated, a feature appear s in the scattering having a fractal-like power-law form Q(-D) (where Q is the scattering wave vector) in the very-low-Q region, extending t o below the limit of the instruments used and which covers a maximum r ange of about one and one-half orders of magnitude in Q. The gradient measured during desorption D, being 1.75+/-0.1 for porous Vycor glass, 1.85+/-0.1 for Ludox, and 2.0+/-0.1 for a silica sol-gel, indicates t hat the percolation network forms a fractal-like geometry under these conditions. The gradient for adsorption is less than 1.0 for both Vyco r and Ludox, and no power-law form of SANS is seen at all for the sili ca sol-gel. This implies that fractal-like percolation networks are no t formed during the adsorption process.