GAS-PHASE MOLECULAR RECOGNITION OF AROMATIC AMINO-ACID AND AROMATIC CARBOXYLIC-ACID GUESTS WITH A SUPRAMOLECULAR CLOPENTADIENYL)RHODIUM(2'-DEOXYADENOSINE)](3)(3-PI INTERACTIONS UTILIZING ELECTROSPRAY-IONIZATION MASS-SPECTROSCOPY() CYCLIC TRIMER HOST VIA NONCOVALENT PI)

Authors
BAKHTIAR R CHEN H OGO S FISH RH
Citation
R. Bakhtiar et al., GAS-PHASE MOLECULAR RECOGNITION OF AROMATIC AMINO-ACID AND AROMATIC CARBOXYLIC-ACID GUESTS WITH A SUPRAMOLECULAR CLOPENTADIENYL)RHODIUM(2'-DEOXYADENOSINE)](3)(3-PI INTERACTIONS UTILIZING ELECTROSPRAY-IONIZATION MASS-SPECTROSCOPY() CYCLIC TRIMER HOST VIA NONCOVALENT PI), Chemical communications, (22), 1997, pp. 2135-2136
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
22
Year of publication
1997
Pages
2135 - 2136
Database
ISI
SICI code
1359-7345(1997):22<2135:GMROAA>2.0.ZU;2-5
Abstract
A novel, gas phase, host-guest molecular recognition process, detected by electrospray ionization mass spectrometry, using guests that encom pass aromatic amino acids and aromatic and aliphatic carboxylic acids with a supramolecular, bioorganometallic host, [CpRh(2'-deoxyadenosin e)](3)[OTf](3) (Cp = eta(5)-C5Me5), is found to occur predominately v ia non-covalent pi-pi interactions; non-covalent hydrophobic forces ap parently being weak or non-existent.