CURING BEHAVIOR OF POLY(VINYL CHLORIDE)-GRAFT-2-HYDROXYETHYL METHACRYLATE

Authors
LEE WF HWONG GY
Citation
Wf. Lee et Gy. Hwong, CURING BEHAVIOR OF POLY(VINYL CHLORIDE)-GRAFT-2-HYDROXYETHYL METHACRYLATE, European Polymer Journal, 33(9), 1997, pp. 1499-1504
Citations number
26
Categorie Soggetti
Polymer Sciences
Journal title
European Polymer Journal → ACNP
ISSN journal
00143057
Volume
33
Issue
9
Year of publication
1997
Pages
1499 - 1504
Database
ISI
SICI code
0014-3057(1997)33:9<1499:CBOPCM>2.0.ZU;2-A
Abstract
Poly(vinyl chloride) was dehydrochlorinated in alkali solution and the n grafted with 2-hydroxyethyl methacrylate (HEMA) using benzoyl peroxi de as an initiator under a nitrogen atmosphere. The solubility of PVC- g-HEMA has been successfully achieved through the addition of poly(HEM A). The curing of the mixture of PVC-g-HEMA and poly(HEMA) effected th rough a blocked diisocyanate was investigated. The investigation invol ved the synthesis of three kinds of blocked diisocyanates and the effe cts of the grafting percentage, curing time, curing temperature and ca talyst. A desired flexible and golden color film can be obtained by co ntrolling the quantity of the curing agent. (C) 1997 Elsevier Science Ltd.