THE RHODIUM-ASSISTED DECOMPOSITION OF DIAZOACETYLACETIC ESTERS

Citation
P. Ceccherelli et al., THE RHODIUM-ASSISTED DECOMPOSITION OF DIAZOACETYLACETIC ESTERS, Synthetic communications, 24(6), 1994, pp. 891-897
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
24
Issue
6
Year of publication
1994
Pages
891 - 897
Database
ISI
SICI code
0039-7911(1994)24:6<891:TRDODE>2.0.ZU;2-K
Abstract
Diazoketones derived from alkoxymalonic acid undergo dirhodium tetraac etate-catalyzed decomposition yielding 4,5-dialkoxy-3(2H)-furanones, w hile those derived from monoesters of dimethylmalonic acid furnish 2.5 -oxidocyclohexanones.