ION-SELECTIVE ELECTRODE FOR BISMUTH(III) IN ETHYLENEDIAMINTETRAACETATE MEDIUM

A coated graphite-epoxy ion-selective electrode for bismuth(III), base d on the ion-pair between the [BI(EDTA)](-) anion and tricaprylylmethy lammonium cation (Aliquat 336S) incorporated onto a poly(vinylchloride ) (PVC) matrix is constructed. A thin membrane film of this ion-pair, dibutylphthalate (DBPh) or ortho-nitrophenyloctylether (o-NPOE) in PVC was deposited directly onto a Perspex(R) tube which contained a graph ite-epoxy conductor substrate attached to the end of a glass tube. The coating solution was prepared by dissolving 30% (w/w) of PVC in 10 ml of tetrahydrofuran following addition of 65% (w/w) DBPh or o-NPOE and 5% (w/w) of the ionic pair. The effect of. pH, EDTA concentration and some cation and anion on the electrode response is investigated. The bismuth(III) ion-selective electrode shows a linear response in the bi smuth(III) concentration range from 1.0 x 10(-8) to 1.0 x 10(-1) mol 1 (-1) and 1.0 x 10(-7) to 1.0 x 10(-1) mol 1(-1) and a slope of 56.8 an d 59.2 mV dec.(-1) for the polymeric membranes containing DBPh and o-N POE, respectively. The lifetime of this electrode was superior to 1 ye ar (over 1600 determinations for each polymeric membrane), with practi cal detection limits of 6.3 x 10(-9) and 4.4 x 10(-8) mol 1(-1) with t hese plasticizers. Application of this electrode with bismuth(III) det ermination in a stomach anti-acid sample is described. (C) 1997 Elsevi er Science B.V.