We present high-resolution spectroscopic observations of LS 4825, a V
= 12 B-type star in the Galactic center direction. On the basis of its
stellar and interstellar spectra, we infer that it is likely to be a
young supergiant at a distance of 21 +/- 5 kpc, and hence lying on the
far side of the 'Galaxy. Adopting this hypothesis, a differential abu
ndance analysis shows LS 4825 to have a chemical composition that is c
onsistent with local B-type supergiants. These observations therefore
represent the first detailed investigation of a star on the far side o
f the Galactic center. We trace multiple interstellar components in Ca
II K and Na I D spectra, with velocities -206 less than or equal to v
(lst) less than or equal to +93 km s(-1). We consider the likely origi
n of this gas and find that some components appear to trace matter lyi
ng close to the Galactic center. We discuss the possible use of such s
ight lines in furthering our understanding both of the nature of gas a
round the Galactic center and of the abundance gradient of the Galaxy.