SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DOUBLE BARIUM-TITANIUM METHOXIDE [BA2TI4O(OME)(18)(MEOH)(7)]CENTER-DOT-MEOH

Authors
STARIKOVA ZA YANOVSKY AI KOTOVA NM YANOVSKAYA MI TUROVA NY BENLIAN D
Citation
Za. Starikova et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DOUBLE BARIUM-TITANIUM METHOXIDE [BA2TI4O(OME)(18)(MEOH)(7)]CENTER-DOT-MEOH, Polyhedron, 16(24), 1997, pp. 4347-4351
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
24
Year of publication
1997
Pages
4347 - 4351
Database
ISI
SICI code
0277-5387(1997)16:24<4347:SACOTD>2.0.ZU;2-P
Abstract
The X-ray diffraction study of crystals isolated from solutions obtain ed by reaction of Ba(OMe)(2) with Ti(OMe)(4) (molar ratio 1 : 2) in me thyl alcohol was carried out, the crystals of the methanol solvate of the double barium-titanium methoxide, [Ba2Ti4O(OMe)(18)(MeOH)(7)]. MeO H (1), contain two Ba2+ cations with different environments and two ki nds of anionic binuclear titanium complexes with and without oxo-ligan d, and thus can be formulated as eOH)(5)](2+)[Ti2O(OMe)(8)](2-)[Ti-2(O Me)(10)](2-). MeOH. (C) 1997 Elsevier Science Ltd.