The complex dielectric functions of beta-rhombohedral boron, of boron
carbide with compositions between B4.23C and B10.37C and YB66, mere me
asured between about 2.5 and 9.5 eV. Similarities of the electronic st
ructures probably due to the icosahedra are indicated by obvious quali
tative similarities of the spcetra, Numerous critical points have been
determined and confirm the dense sequence of energy bands, For beta-r
hombohedral boron the critical points are compatible with the combined
density of states maxima derived from cluster calculations by K. Shir
ai and H. Nakamatsu (1994, in ''Proc. 11th Int. Symp. Boron, Borides a
nd Related Comp, Tsukuba, 1993,'' JJAP Series 10, p. 70), Otherwise no
satisfactory correlation with theoretical band structure calculations
is possible, In the case of boron carbide the critical points art the
same within the whole homogeneity range, while the values of the diel
ectric function at higher energies indicate composition-dependent dens
ities of states, which are correlated with the density of B-12 icosahe
dra. (C) 1997 Academic Press.