H. Werheit et al., EVIDENCE OF THE RELATIONSHIP OF THE ELECTRONIC-PROPERTIES OF ICOSAHEDRAL BORON-RICH SOLIDS AND ICOSAHEDRAL QUASI-CRYSTALS, Journal of solid state chemistry, 133(1), 1997, pp. 160-163
Optical conductivities and dielectric functions derived from the IR-op
tical reflectivity spectra exhibit clear similarities between icosahed
ral boron-rich structures and Al-based isosahedral quasicrystals. This
suggests a close qualitative relationship of their electronic structu
res. Accordingly icosahedral quasicrystals are assumed to be semicondu
ctors with complex band structures qualitatively related to those of b
oron-rich solids, which are essentially determined by electron-phonon
interactions. (C) 1997 Academic Press.