F. Thevenot et al., BORON-NITRIDE OBTAINED FROM MOLECULAR PRECURSORS - AMINOBORANES USED AS A BN SOURCE FOR COATINGS, MATRIX, AND SI3N4BN COMPOSITE CERAMIC PREPARATION, Journal of solid state chemistry, 133(1), 1997, pp. 164-168
Aminoboranes, pure or partially converted into aminoborazines using th
ermal or aminolysis polymerization, have been used as boron nitride pr
ecursors. An amorphous BN preceramic is obtained when pyrolysed up to
1000 degrees C that can be stabilized using further annealing up to 14
00 degrees C or crystallized into h-BN above 1700 degrees C. These mol
ecular precursors have been used to prepare carbon fiber/BN matrix mic
rocomposites to get an efficient BN coating on graphite and as a BN so
urce in Si3N4/BN composite ceramic. The properties of these new types
of samples have been compared with those obtained by classical process
es. The boron nitride obtained from these precursors is a good sinteri
ng agent during the hot-pressing of the samples. However, the crystall
inity of BN, even sintered up to 1800 degrees C, remains poor. In fact
, most of the mechanical properties of the composite ceramic (density,
porosity, hardness) are clearly improved and the aminoboranes san be
considered as convenient boron nitride sources and helpful sintering a
gents in hot-pressing technology. (C) 1997 Academic Press.