M. Fukawa et al., DEVELOPMENT OF TEMPERED-GLASS SUBSTRATES WITH TCO FILMS FOR A-SI SOLAR-CELLS, Solar energy materials and solar cells, 49(1-4), 1997, pp. 107-112
Tempered-glass substrates with transparent conductive oxide (TCO) film
s were developed for a-Si solar cells using an air blasting method. Th
e mechanism of thermal deflection arising from the difference of therm
al properties between glass and TCO films was investigated using in si
tu X-ray diffraction method during heating and cooling processes. It w
as found that the deflection was caused by tensile stress induced in t
he films at a high temperature above 600 degrees C as well as the diff
erence of thermal expansion coefficient between glass and TCO films. I
n addition, the stress was found to be closely correlated to the depos
ition temperature of the TCO films. Tempered glass with TCO films with
small deflection, which passed strength test using a steel ball (227
g, 2.5 m height), was obtained by increasing the deposition temperatur
e of the TCO films.