H. Katagiri et al., PREPARATION AND EVALUATION OF CU2ZNSNS4 THIN-FILMS BY SULFURIZATION OF E-B EVAPORATED PRECURSORS, Solar energy materials and solar cells, 49(1-4), 1997, pp. 407-414
By sulfurization of E-B evaporated precursors, CZTS(Cu2ZnSnS4) films c
ould be prepared successfully. This semiconductor does not consist of
any rare-metal such as In. The X-ray diffraction pattern of CZTS thin
films showed that these films had a stannite structure. This study est
imated the optical band gap energy as 1.45 eV. The optical absorption
coefficient was in the order of 10(4) cm(-1). The resistivity was in t
he the order of 10(4) Ohm cm and the conduction type was p-type. Fabri
cated solar cells, Al/ZnO/CdS/CZTS/Mo/Soda Lime Glass, showed an open-
circuit voltage up to 400 mV.