SYNTHESIS, CHARACTERIZATION AND THERMAL-BEHAVIOR OF CALCIUM AND STRONTIUM 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE COMPLEXES - CRYSTAL-STRUCTURE OF R(MU,ETA(2)-THD)(ETA(2)-THD)(ETA(2)-MEOC2H4OH)](2)

Authors
GUILLON H HUBERTPFALZGRAF LG VAISSERMANN J
Citation
H. Guillon et al., SYNTHESIS, CHARACTERIZATION AND THERMAL-BEHAVIOR OF CALCIUM AND STRONTIUM 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE COMPLEXES - CRYSTAL-STRUCTURE OF R(MU,ETA(2)-THD)(ETA(2)-THD)(ETA(2)-MEOC2H4OH)](2), Silicon, germanium, tin and lead compounds, 20(10), 1997, pp. 633-639
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Silicon, germanium, tin and lead compounds → ACNP
ISSN journal
07921241
Volume
20
Issue
10
Year of publication
1997
Pages
633 - 639
Database
ISI
SICI code
0792-1241(1997)20:10<633:SCATOC>2.0.ZU;2-B
Abstract
The reaction between oligomeric alkaline earth metal tetramethylheptan edionates [M(thd)(2)](m) (M = Sr, Ca) with 2-methoxyethanol, yielded t he adducts [M(thd)(2)(MeOC2H4OH)](m)[M = Sr (1), Ca (2)] which were ch aracterized by elemental analysis, IR and H-1 NMR spectroscopy. Compou nd 1 has been characterized by single crystal X-Ray diffraction as a d imer Sr(mu,h(2)-thd)(eta(2)-thd)(eta(2)-MeOC2H4OH)](2). The Sr-O bond lengths spread over the range 2.390(7)-2.755(8) Angstrom, the order of variation being Sr-O(thd) < Sr-O(OH)< Sr-O(OCH3). Thermogravimetric a nalysis data and volatility are discussed for both compounds.