THE FIRST EXAMPLE OF SYNTHESIS OF ALUMINACYCLOPROPANES CATALYZED BY (ETA(5)-C5H5)(2)TICL2

Authors
DZHEMILEV UM IBRAGIMOV AG KHAFIZOVA LO RUSAKOV SV KHALILOV LM
Citation
Um. Dzhemilev et al., THE FIRST EXAMPLE OF SYNTHESIS OF ALUMINACYCLOPROPANES CATALYZED BY (ETA(5)-C5H5)(2)TICL2, Mendeleev communications, (5), 1997, pp. 198-199
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
5
Year of publication
1997
Pages
198 - 199
Database
ISI
SICI code
0959-9436(1997):5<198:TFEOSO>2.0.ZU;2-8
Abstract
The synthesis of a series of cyclic organoaluminium compounds, alumina cyclopropanes, which have never previously been described, has been ca rried out by alpha-olefin cyclometallation with EtAlCl2 in the presenc e of a chlorine ion acceptor, metallic magnesium and Cp2TiCl2(Cp = eta (5)-C5H5) catalyst.