O-(3-STANNYLPROPYLOXY) CARBOHYDRATE-DERIVATIVES VIA HYDROSTANNYLATIONOF O-ALLYL CARBOHYDRATE COMPOUNDS

Authors
GARDEN SJ WARDELL JL
Citation
Sj. Garden et Jl. Wardell, O-(3-STANNYLPROPYLOXY) CARBOHYDRATE-DERIVATIVES VIA HYDROSTANNYLATIONOF O-ALLYL CARBOHYDRATE COMPOUNDS, Silicon, germanium, tin and lead compounds, 20(11), 1997, pp. 711-721
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Silicon, germanium, tin and lead compounds → ACNP
ISSN journal
07921241
Volume
20
Issue
11
Year of publication
1997
Pages
711 - 721
Database
ISI
SICI code
0792-1241(1997)20:11<711:OCVH>2.0.ZU;2-M
Abstract
Various O-(3-triorganostannyl)propyl carbohydrate derivatives have bee n synthesised by hydrostannylation of selected O-allyl mannose, glucos e and lactose derivatives, containing both protected and free hydroxyl groups, and possessing either furanose and pyranose rings: both mono- and disaccharide derivatives have been obtained. Characterisation of t he products has been carried out using H-1, C-13 and Sn-119 NMR spectr oscopy. The conformations of the carbohydrate rings are not affected b y the large, but remote, organotin substituents.