EPOXIDATION BY DIMETHYLDIOXIRANE - KINETICS FOR CIS-ALKENES

Authors
BAUMSTARK AL MICHELENABAEZ E NAVARRO AM BANKS HD
Citation
Al. Baumstark et al., EPOXIDATION BY DIMETHYLDIOXIRANE - KINETICS FOR CIS-ALKENES, Heterocyclic communications, 3(5), 1997, pp. 393-396
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocyclic communications → ACNP
ISSN journal
07930283
Volume
3
Issue
5
Year of publication
1997
Pages
393 - 396
Database
ISI
SICI code
0793-0283(1997)3:5<393:EBD-KF>2.0.ZU;2-K
Abstract
Kinetic data for epoxidation of a series of cis-alkenes and cycloalken es by dimethyldioxirane in dried acetone are reported; the results are consistent with a concerted, electrophilic process with a spiro-trans ition state.