T. Egami et al., LOCAL ATOMIC-STRUCTURE OF RELAXOR FERROELECTRIC SOLIDS DETERMINED BY PULSED-NEUTRON AND X-RAY-SCATTERING, Ferroelectrics, 199(1-4), 1997, pp. 103-113
The origin of relaxer Ferroelectric behavior is complex, and is likely
to include both compositional as well as structural order and disorde
r. Non-crystallographic methods of structural study by pulsed neutron
and synchrotron X-ray scattering applied to these solids reveal mas-si
ve local displacive disorder and short range compositional order in th
ese solids. Examples of such local structural complexities in PMN and
PLZT are discussed.