Vv. Lemanov et Vk. Yarmarkin, DEPOLARIZATION FIELD AS A DRIVING-FORCE OF FATIGUE IN PZT FERROELECTRIC THIN-FILMS, Ferroelectrics, 201(1-4), 1997, pp. 55-64
A study has been made of the dependence of switched charge in ferroele
ctric lead-zirconate-titanate films on the number of polarization reve
rsal cycles produced by bipolar voltage pulses of fixed amplitude and
duration under variation of their repetition rate. The film fatigue in
the polarization switching frequency range studied (100 Hz - 100 kHz)
has been shown to be dominated by the depolarization field caused by
the presence in the near-electrode film regions of a pyrochlore-struct
ure nonferroelectric phase.