EXTRACTION OF CE(III) AND EU(III) BY NITROBENZENE SOLUTIONS OF BIS-1,2-DICARBOLLYLCOBALTATE IN THE PRESENCE OF 18-CROWN-6

Citation
P. Vanura et al., EXTRACTION OF CE(III) AND EU(III) BY NITROBENZENE SOLUTIONS OF BIS-1,2-DICARBOLLYLCOBALTATE IN THE PRESENCE OF 18-CROWN-6, Solvent extraction and ion exchange, 12(2), 1994, pp. 439-458
Citations number
19
Categorie Soggetti
Chemistry
ISSN journal
07366299
Volume
12
Issue
2
Year of publication
1994
Pages
439 - 458
Database
ISI
SICI code
0736-6299(1994)12:2<439:EOCAEB>2.0.ZU;2-A
Abstract
The extraction of Ce(III) and Eu(III) by nitrobenzene solutions of bis -1,2-dicarbollylcobaltate anions in the presence of 18-crown-6 from aq ueous solutions of nitric acid has been investigated. Distribution rat ios, the protonization and exchange extraction constants for the inves tigated systems has been determined. The calculated values of distribu tion ratios D have been compared with experimental ones.