A multiple scattering formulation for the electromigration wind force
on atoms in dilute alloys is developed. The theory describes electromi
gration via a vacancy mechanism. The method is used to calculate the w
ind valence for electromigration in various host metals having a close
-packed lattice structure, namely aluminum, the noble metals copper, s
ilver, and gold, and the 4d transition metals. The self-electromigrati
on results for aluminum and the noble metals compare well with experim
ental data. For the 4d metals small wind valences are found, which mak
e these metals attractive candidates for the experimental study of the
direct valence.