H. Overhof et al., THERMOPOWER AND CONDUCTIVITY ACTIVATION-ENERGIES IN HYDROGENATED AMORPHOUS-SILICON - COMMENT, Physical review. B, Condensed matter, 56(19), 1997, pp. 12649-12650
In a recent Brief Report [Phys. Rev. B 54, 7630 (1996)] Dyalsingh and
Kakalios compared activation energies of transport data for doped a-Si
:H. They confirmed once more that the activation energy of the de cond
uctivity is larger by a tenth of an eV than the activation energy of t
he thermoelectric power. In addition, the activation energy of the sho
rt-circuit current in the presence of a thermal gradient for the same
samples is examined. The authors found that this latter activation ene
rgy coincides exactly with the activation energy of the de conductivit
y and that also the absolute values of both conductivities are practic
ally identical. They conclude that this latter finding is a strong ind
ication for the presence of long-ranged potential and/or compositional
disorder. In this paper we show that the latter result simply follows
from Ohm's law and, therefore, gives no support to any specific trans
port model.