CADMIUM NANOCLUSTERS WITH PHENYLSELENOLATO-LIGANDS AND PHENYLTELLUROLATO-LIGANDS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [CD17SE4(SEPH)(24)(PPH3)(4)][CD8SE(SEPH)(12)CL-4], [CD(DMF)(6)][CD8SE(SEPH)(12)CL-4], [CD8SE(SEPH)(14)(PPH3)(2)], [CD8SE(SEPH)(14)(DMF)(3)] AND [CD8TE(TEPH)(14)(PET3)(3)]

Authors
BEHRENS S FENSKE D
Citation
S. Behrens et D. Fenske, CADMIUM NANOCLUSTERS WITH PHENYLSELENOLATO-LIGANDS AND PHENYLTELLUROLATO-LIGANDS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [CD17SE4(SEPH)(24)(PPH3)(4)][CD8SE(SEPH)(12)CL-4], [CD(DMF)(6)][CD8SE(SEPH)(12)CL-4], [CD8SE(SEPH)(14)(PPH3)(2)], [CD8SE(SEPH)(14)(DMF)(3)] AND [CD8TE(TEPH)(14)(PET3)(3)], Berichte der Bunsengesellschaft fur Physikalische Chemie, 101(11), 1997, pp. 1588-1592
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
ISSN journal
00059021 → ACNP
Volume
101
Issue
11
Year of publication
1997
Pages
1588 - 1592
Database
ISI
SICI code
0005-9021(1997)101:11<1588:CNWPAP>2.0.ZU;2-E
Abstract
A method of synthesis for cadmium selenide and cadmium telluride clust ers is proposed. PhSeSiMe3 reacts with [CdCl2(PPh3)(2)] to yield a ser ies of cadmium selenide clusters depending on the kind of solvent used . The reaction of PhTeSiMe3 with CdCl2 and PEt3 yields a cadmium tellu ride cluster. Crystalline products suitable for single-crystal X-ray a nalysis could be obtained. We describe the molecular structures of [Cd 17Se4(SePh)(24)(PPh3)(4)][Cd8Se(SePh)(12)Cl-4] (1), [Cd(DMF)(6)][Cd8Se (SePh)(12)Cl-4] (2), [Cd8Se(SePh)(14)(PPh3)(2)] (3), [Cd8Se(SePh)(14)( DMF)(3)] (4) and [Cd8Te(TePh)(14)(PEt3)(3)] (5).