EXCITATION AND STABILITY OF ULTRAHIGH RYDBERG STATES IN STRAY ELECTRIC-FIELDS

Citation
P. Bellomo et al., EXCITATION AND STABILITY OF ULTRAHIGH RYDBERG STATES IN STRAY ELECTRIC-FIELDS, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(47), 1997, pp. 8902-8907
Citations number
34
Categorie Soggetti
Chemistry Physical
ISSN journal
10895639
Volume
101
Issue
47
Year of publication
1997
Pages
8902 - 8907
Database
ISI
SICI code
1089-5639(1997)101:47<8902:EASOUR>2.0.ZU;2-K
Abstract
We demonstrate the feasibility of exciting long-lived, circular Rydber g states by time dependent weak electric fields such as might be encou ntered in typical ZEKE-PES (zero-electron-kinetic-energy photoelectron spectroscopy) conditions. Through a geometric interpretation of the d ynamics, we identify the field configurations needed for either the st ability or the excitation of ultra-long-living Rydberg states and conc lude that nonuniform stray fields could be (partially) responsible for the observed, anomalously long lifetimes exhibited by ultrahigh Rydbe rg states, although under typical ZEKE-PES conditions other mechanisms like, for example, ion-Rydberg collisions constitute the main stabili zation agent.