O. Roetting et G. Hinrichsen, RHEOLOGICAL CONDITIONS FOR THE DEVELOPMENT OF FIBRILS IN BLENDS OF LIQUID-CRYSTALLINE AND CONVENTIONAL POLYMERS, Journal of thermoplastic composite materials, 10(6), 1997, pp. 524-531
In blends of liquid crystalline polymers (LCP) with conventional therm
oplastics, the development of infinite, thin and highly oriented LCP-f
ibrils is very important for a substantial mechanical reinforcement of
the blends. Such fibrils can be produced by processing a coarse mixtu
re of LCP and polyethyleneterephthalate (PET) powders in an extrusion
apparatus in which preferentially elongational, but only weak shear fl
ows occur. The rheological conditions for the success of this process
are explained.