T. Seckin et al., PREPARATION AND CHARACTERIZATION OF A CLAY-POLYVINYLPYRIDINIUM MATRIXFOR THE REMOVAL OF BACTERIAL-CELLS FROM WATER, Journal of Materials Science, 32(22), 1997, pp. 5993-5999
Polyvinylpyridinium salts were immobilized onto a clay matrix and were
then tested for their antibacterial properties. The clay-polyvinylpyr
idinium matrix was prepared by the copolymerization of gamma-methacryl
oxypropyltriethoxy silane bonded covalently to clay and 4-vinylpyridin
e and subsequent quaternization with benzyl halides. Suspension tests
for antibacterial properties of the immobilized bactericide against Es
cherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa demo
nstrated the high activity of the pyridinium salts that are bonded to
the polyacrylate spacer. Advantageously, these insoluble clay-polymer
bactericides could be applied without any contamination by the substra
te.