EXAFS STUDY OF SUPPORTED TICL4 MGCL2 CATALYST

Authors
POTAPOV AG KRIVENTSOV VV KOCHUBEY DI BUKATOV GD ZAKHAROV VA
Citation
Ag. Potapov et al., EXAFS STUDY OF SUPPORTED TICL4 MGCL2 CATALYST, Macromolecular chemistry and physics, 198(11), 1997, pp. 3477-3484
Citations number
10
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular chemistry and physics → ACNP
ISSN journal
10221352
Volume
198
Issue
11
Year of publication
1997
Pages
3477 - 3484
Database
ISI
SICI code
1022-1352(1997)198:11<3477:ESOSTM>2.0.ZU;2-C
Abstract
Extended X-ray absorption fine structure analysis (EXAFS) has been use d to study supported TiCl4/MgCl2 catalysts containing 1.8 wt.-% Ti. Ad sorbed TiCl4 was found to exist on the MgCl2 surface as a dimeric comp lex. The possible structures of dimeric TiCl4 complexes on the (100) f ace of MgCl2 are discussed.