SYNTHESIS, CHARACTERIZATION, AND CATALYTIC BEHAVIOR OF RUTHENIUM(II) SCHIFF-BASE COMPLEXES

Authors
SERRON SA HAAR CM NOLAN SP BRAMMER L
Citation
Sa. Serron et al., SYNTHESIS, CHARACTERIZATION, AND CATALYTIC BEHAVIOR OF RUTHENIUM(II) SCHIFF-BASE COMPLEXES, Organometallics, 16(23), 1997, pp. 5120-5123
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
23
Year of publication
1997
Pages
5120 - 5123
Database
ISI
SICI code
0276-7333(1997)16:23<5120:SCACBO>2.0.ZU;2-#
Abstract
The complexes (X-6-acen)Ru(PPh3)(2) (X = H (1) and F (2)) have been pr epared and characterized by standard spectroscopic and analytical meth ods. Additionally, the solid-state structure of 2 has been determined by single-crystal X-ray diffraction. Ligand exchange reactions involvi ng the labile Ru-PPh3 bond are easily performed, and complex 1 serves as a catalyst precursor for the isomerization of 1-hexene.