BUTADIENE AND STYRENE POLYMERIZATION AND THEIR COPOLYMERIZATION WITH A NICKEL-CATALYST SYSTEM

Authors
GEHRKE K KOSMELLA HJ
Citation
K. Gehrke et Hj. Kosmella, BUTADIENE AND STYRENE POLYMERIZATION AND THEIR COPOLYMERIZATION WITH A NICKEL-CATALYST SYSTEM, Kautschuk und Gummi, Kunststoffe, 50(11), 1997, pp. 793-799
Citations number
10
Categorie Soggetti
Polymer Sciences","Engineering, Chemical
Journal title
Kautschuk und Gummi, Kunststoffe → ACNP
ISSN journal
09483276
Volume
50
Issue
11
Year of publication
1997
Pages
793 - 799
Database
ISI
SICI code
0948-3276(1997)50:11<793:BASPAT>2.0.ZU;2-V
Abstract
Butadiene and styrene were polymerized with the Ziegler-Nattacatalyst system Ni(naph)(2)/Al1.65F1.35. The influence of temperature, monomer, concentration and catalyst concentration on conversion, molecular wei ght and cis-1.4-content of polybutadiene and tacticity of polystyrene were investigated, Furthermore the copolymerization butadiene/styrene with the same catalyst was realized and the reaction reactivities dete rmined.