Low-field tunneling magnetoresistance was observed in films of half-me
tallic CrO2 that were grown by high-pressure thermal decomposition of
CrO3. High-temperature annealing treatments modified the intergrain ba
rriers of the as-grown films through surface decomposition of CrO2 int
o insulating Cr2O3, which led to a threefold enhancement of the low-fi
eld magnetoresistance. This enhancement indicates the potential of thi
s simple method to directly control the interface barrier characterist
ics that determine the magnetotransport properties.