FACILE HYDROGEN-TRANSFER REDUCTION OF MULTIPLE BONDS BY FORMIC-ACID CATALYZED WITH A PD-561 GIANT CLUSTER

Authors
MOISEEV II TSIRKOV GA GEKHMAN AE VARGAFTIK MN
Citation
Ii. Moiseev et al., FACILE HYDROGEN-TRANSFER REDUCTION OF MULTIPLE BONDS BY FORMIC-ACID CATALYZED WITH A PD-561 GIANT CLUSTER, Mendeleev communications, (1), 1997, pp. 1-3
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
1
Year of publication
1997
Pages
1 - 3
Database
ISI
SICI code
0959-9436(1997):1<1:FHROMB>2.0.ZU;2-D
Abstract
A palladium-561 giant cluster/HCOOH hydrogen-transfer reduction system has been found to be efficient for the liquid-phase hydrogenation of aromatic and aliphatic compounds with N=O, C drop N, C=O and C=C bonds under mild conditions; the reduction of nitriles is accompanied by me tathesis of amines under unusually mild conditions.