FIRST REPRESENTATIVES OF MACROCYCLIC POLY(DIAZENE OXIDE FURAZANS) - 3,4 14-OCTAAZACYCLOHEXADECA-1,3,5,7,9,11,13,15-OCTAENE 1,9-DIOXIDE AND 1,10-DIOXIDE - 1,5,9,13-TETRAOXIDE AND ITS CRYSTAL-STRUCTURE/
Va. Eman et al., FIRST REPRESENTATIVES OF MACROCYCLIC POLY(DIAZENE OXIDE FURAZANS) - 3,4 14-OCTAAZACYCLOHEXADECA-1,3,5,7,9,11,13,15-OCTAENE 1,9-DIOXIDE AND 1,10-DIOXIDE - 1,5,9,13-TETRAOXIDE AND ITS CRYSTAL-STRUCTURE/, Mendeleev communications, (1), 1997, pp. 5-7
Macrocyclic poly(diazene oxide furazans) have been synthesised for the
first time: the tetraoxide was prepared by the oxidation of diazene f
ragments in the tetradiazenofurazan macrocycle, and the dioxides were
synthesised by the intramolecular and intermolecular oxidative cyclisa
tion of structures already containing diazene oxide fragments. The str
ucture of the tetraoxide derivative has been established by X-ray diff
raction analysis.