K. Muto et al., THERMALLY STABLE ENVIRONMENTAL CATALYST - OXIDATION OF METHANE OVER CALCINED PALLADIUM LOADED ON SILICA MONOLAYER, Catalysis today, 35(1-2), 1997, pp. 145-151
Enhancement of thermal stability of the Pd loaded on alumina for the c
omplete oxidation of hydrocarbons was studied by preparing the surface
of a support consisting of a partially covered silica monolayer and r
emaining alumina by a chemical vapor deposition of silicon alkoxide. T
he thermal stability of the Pd-loaded silica-deposited alumina was tes
ted after the calcination at 1493 K. The silica monolayer not only mai
ntained the high surface area, but also suppressed the sintering of pa
lladium. After the calcination, the catalytic activity of Pd/10 wt% Si
O2/Al2O3 was double that on Pd/Al2O3, although it decreased to 1/10 of
the initial activity. The support and loaded palladium were character
ized by BET, XRD, TEM and TPR measurements.