S. Dari et al., DIPOLE-MOMENT CALCULATIONS IN MOLECULES WITH CHARGED ATOMS (ZWITTERIONIC FORMS) - MESOMERIC MOMENTS, Journal of molecular structure, 318, 1994, pp. 211-216
A practical method of dipole moment calculation of molecules with char
ged atoms is presented. The method is a combination of the classical b
ond moments additivity method and of electrostatic calculations taking
into account interactions between charges and polarizable atoms. The
method is tested successfully on simple zwitterionic species and then
applied to molecules with mesomeric forms. The conjugation effects are
well represented by the method which gives reasonable values for the
corresponding mesomeric moments and complementary information on the p
ercentages of the mesomeric forms.