OLIGOMERIZATION CHEMISTRY OF A METALLABENZENE CYCLOADDUCT - SYNTHESISAND STRUCTURE OF AN ORGANOMETALLIC CROWN COMPOUND

Authors
BLEEKE JR BEHM R BEATTY AM
Citation
Jr. Bleeke et al., OLIGOMERIZATION CHEMISTRY OF A METALLABENZENE CYCLOADDUCT - SYNTHESISAND STRUCTURE OF AN ORGANOMETALLIC CROWN COMPOUND, Organometallics, 16(6), 1997, pp. 1103-1105
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
6
Year of publication
1997
Pages
1103 - 1105
Database
ISI
SICI code
0276-7333(1997)16:6<1103:OCOAMC>2.0.ZU;2-3
Abstract
The CS2 adduct of ''iridabenzene'' undergoes dimerization and cyclotri merization reactions by linking subunits through thiocarbonyl sulfur c enters. The cyclotrimerization product (compound 4) has been structura lly characterized and contains a novel organometallic trithia-12-crown -3 ring system.