NITROUS-OXIDE MEDIATED OXYGEN-ATOM INSERTION INTO A RUTHENIUM-HYDRIDEBOND - SYNTHESIS AND REACTIVITY OF THE MONOMERIC HYDROXORUTHENIUM COMPLEX (DMPE)(2)RU(H)(OH)

Authors
KAPLAN AW BERGMAN RG
Citation
Aw. Kaplan et Rg. Bergman, NITROUS-OXIDE MEDIATED OXYGEN-ATOM INSERTION INTO A RUTHENIUM-HYDRIDEBOND - SYNTHESIS AND REACTIVITY OF THE MONOMERIC HYDROXORUTHENIUM COMPLEX (DMPE)(2)RU(H)(OH), Organometallics, 16(6), 1997, pp. 1106-1108
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
6
Year of publication
1997
Pages
1106 - 1108
Database
ISI
SICI code
0276-7333(1997)16:6<1106:NMOIIA>2.0.ZU;2-V
Abstract
Treatment of (DMPE)(2)Ru(H)(2) with 1 equiv of N2O affords the hydroxo ruthenium complex (DMPE)(2)Ru(H)(OH) (1) in 41% yield; further treatme nt with an atmosphere of N2O affords the bis(hydroxo) complex (DMPE)(2 )Ru(OH)(2) (4) in 17% yield. The addition of protic reagents to 1 resu lts in the replacement of the OH group with several other ligands, inc luding aryloxo, thiolato, siloxo, C-bound enolate, acetylide, and trip henylstannyl; more deep-seated changes take place when 1 reacts with p -tolualdehyde and hexafluoroacetone.