SYNTHESIS AND STRUCTURE OF [PB(2-PY)(3)LI-CENTER-DOT-THF], CONTAININGA LOW-VALENT GROUP-14 TRIS(PYRIDYL) LIGAND (2-PY EQUALS 2-PYRIDYL)

Authors
BESWICK MA DAVIES MK RAITHBY PR STEINER A WRIGHT DS
Citation
Ma. Beswick et al., SYNTHESIS AND STRUCTURE OF [PB(2-PY)(3)LI-CENTER-DOT-THF], CONTAININGA LOW-VALENT GROUP-14 TRIS(PYRIDYL) LIGAND (2-PY EQUALS 2-PYRIDYL), Organometallics, 16(6), 1997, pp. 1109-1110
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
6
Year of publication
1997
Pages
1109 - 1110
Database
ISI
SICI code
0276-7333(1997)16:6<1109:SASO[C>2.0.ZU;2-C
Abstract
The reaction of [2-PyLi] with [Cp(2)Pb] produces [Pb(2-Py)(3)Li . THF] (1), containing the first example of a Lore oxidation state group 14 tris(pyridyl) ligand. The solid-state structure of 1 is that of a cage resulting from the symmetrical complexation of the Li+ cation by all the pyridyl-N centers of the [Pb(2-Py)(3)](-) anion.