SYNTHESIS, STRUCTURE, AND HYDRIDE-DEUTERIDE EXCHANGE STUDIES OF CPMOH(3)(PME(2)PH)(2) AND THEORETICAL-STUDIES OF THE CPMOH(3)(PME(3))(2) MODEL SYSTEM

Citation
F. Abugideiri et al., SYNTHESIS, STRUCTURE, AND HYDRIDE-DEUTERIDE EXCHANGE STUDIES OF CPMOH(3)(PME(2)PH)(2) AND THEORETICAL-STUDIES OF THE CPMOH(3)(PME(3))(2) MODEL SYSTEM, Organometallics, 16(6), 1997, pp. 1179-1185
Citations number
54
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
02767333
Volume
16
Issue
6
Year of publication
1997
Pages
1179 - 1185
Database
ISI
SICI code
0276-7333(1997)16:6<1179:SSAHES>2.0.ZU;2-P
Abstract
The synthesis and characterization of CpMoH(3)(PMe(2)Ph)(2), 1, is des cribed. Compound 1 is obtained from the reaction between CpMoCl(3), PM e(2)Ph, and LiAlH4, in 61% yield. Compound 1 has also been obtained fr om the reaction of CpMo(o-C(6)H(4)PMe(2))(PMe(2)Ph)(2) with H-2. Chara cterization of 1 by H-1- and P-31-NMR spectroscopies shows a high degr ee of fluxionality for the hydride atoms, even at low temperatures. A single-crystal X-ray structure indicates that the geometry is pseudo-o ctahedral, with a relative mer arrangement of the three H ligands and the two PMe(2)Ph ligands occupying relative trans positions. This is i n contrast with the only other previously reported structure of a Mo(I V) trihydride, CpMoH3(dppe), which adopts a pseudo trigonal prismatic structure. The Mo-P (average 2.41(8); Angstrom) and Mo-H distances (a verage 1.64(4) Angstrom) are similar to those found in CpMoH3(dppe). The closest H-H distance is 1.79 Angstrom consistent with a classical hydride. The results of ab initio calculations for the CpMoH(3)(PMe(3) )(2) model in different configurations agree with the experimental obs ervations and suggest that a mechanism of hydride exchange consisting of a Bailar twist, which interconverts pseudo-octahedral mer, trans an d fac geometries, is possible. The process of hydride-deuteride exchan ge of 1 in C6D6 is also examined.