F. Abugideiri et al., SYNTHESIS, STRUCTURE, AND HYDRIDE-DEUTERIDE EXCHANGE STUDIES OF CPMOH(3)(PME(2)PH)(2) AND THEORETICAL-STUDIES OF THE CPMOH(3)(PME(3))(2) MODEL SYSTEM, Organometallics, 16(6), 1997, pp. 1179-1185
The synthesis and characterization of CpMoH(3)(PMe(2)Ph)(2), 1, is des
cribed. Compound 1 is obtained from the reaction between CpMoCl(3), PM
e(2)Ph, and LiAlH4, in 61% yield. Compound 1 has also been obtained fr
om the reaction of CpMo(o-C(6)H(4)PMe(2))(PMe(2)Ph)(2) with H-2. Chara
cterization of 1 by H-1- and P-31-NMR spectroscopies shows a high degr
ee of fluxionality for the hydride atoms, even at low temperatures. A
single-crystal X-ray structure indicates that the geometry is pseudo-o
ctahedral, with a relative mer arrangement of the three H ligands and
the two PMe(2)Ph ligands occupying relative trans positions. This is i
n contrast with the only other previously reported structure of a Mo(I
V) trihydride, CpMoH3(dppe), which adopts a pseudo trigonal prismatic
structure. The Mo-P (average 2.41(8); Angstrom) and Mo-H distances (a
verage 1.64(4) Angstrom) are similar to those found in CpMoH3(dppe).
The closest H-H distance is 1.79 Angstrom consistent with a classical
hydride. The results of ab initio calculations for the CpMoH(3)(PMe(3)
)(2) model in different configurations agree with the experimental obs
ervations and suggest that a mechanism of hydride exchange consisting
of a Bailar twist, which interconverts pseudo-octahedral mer, trans an
d fac geometries, is possible. The process of hydride-deuteride exchan
ge of 1 in C6D6 is also examined.