The stability of chemically and electrochemically polymerized polypyrr
ole and its composites has been investigated. The results demonstrate
that the oxidative degradation of polypyrrole and the interruption of
the percolation path of the composites can cause a strong decrease in
electrical conductivity. The possible mechanisms of oxidative degradat
ion of polypyrrole and the interruption of the percolation path of the
composites are also discussed.