SYNTHESIS AND STRUCTURE OF MNGE4S10-CENTER-DOT(C6H14N2)CENTER-DOT-3H2O - A NOVEL SULFIDE FRAMEWORK ANALOGOUS TO ZEOLITE LI-A(BW)

Authors
CAHILL CL PARISE JB
Citation
Cl. Cahill et Jb. Parise, SYNTHESIS AND STRUCTURE OF MNGE4S10-CENTER-DOT(C6H14N2)CENTER-DOT-3H2O - A NOVEL SULFIDE FRAMEWORK ANALOGOUS TO ZEOLITE LI-A(BW), Chemistry of materials, 9(3), 1997, pp. 807-811
Citations number
32
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Chemistry of materials → ACNP
ISSN journal
08974756
Volume
9
Issue
3
Year of publication
1997
Pages
807 - 811
Database
ISI
SICI code
0897-4756(1997)9:3<807:SASOM>2.0.ZU;2-2
Abstract
Single crystals of Dabco-MnGS-SB1 (MnGe4S10 (C6H14N2). 3H(2)O) were sy nthesized hydrothermally in the presence of Dabco (1,4-diazabicyclo[2. 2.2]octane). This material (Pna2(1), a = 18.367(2), b = 14.184(2), and c = 9.410(1) A) contains [Ge4S10](4-) adamantine clusters corner-link ed through distorted Mn2+ centers. The alternating Mn2+ centers and [G e4S10](4-) clusters Lie at the nodes of a distorted Li-A(BW) net conta ining elliptical 8-rings. Channels defined by these 8-rings contain th e template and water molecules. The distortion of S-Mn-S from the idea l tetrahedral angles is a result of the strain associated with ring sy stem of the framework.