Copper samples were exposed at six sites with known ambient parameters
in Argentina and the atmospheric corrosion was investigated after dif
ferent outdoor exposition periods. Weight-loss measurements used to de
termine corrosion damage were complemented with both DC and AC electro
chemical techniques, performed in 0.1 M Na2SO4 solution employing the
exposed face of the test samples, in order to characterize the protect
ivenesses of the surface layers generated on copper in the distinct en
vironments. While the ambient aggressiveness could be well evaluated f
rom meteorological and pollution parameters and from weight-loss data,
the product protective characteristics estimated through SEM and EDAX
observations and electrochemical methods yielded valuable information
to understand mechanistic aspects concerning the effects of physical
properties, structure and contaminant content of surface corrosion pro
ducts. (C) 1997 Elsevier Science Ltd.