Gg. Talanova et al., SYNTHESIS, NMR AND MASS-SPECTROMETRIC INVESTIGATION OF A NEW MULTINUCLEAR SILVER(I) COMPLEX WITH PHOSPHORUS-CONTAINING, SULFUR-CONTAINING LIGAND, Journal of coordination chemistry, 40(3), 1996, pp. 237-246
The new multinuclear coordination compound [Ag-3(LH)(2)]NO3 (where L i
s Ph(2)P(S)CH2P(S)Ph(2)) was synthesized by deprotonation of the compl
ex AgLNO(3) with Et(3)N. On the basis of H-1 and P-31 NMR spectroscopi
c data combined with a mass spectrometric examination in FD and FAB va
riants the complexcation [Ag(L-H)(2)](+) was presumed to consist of a
metallomacrocyclic unit [Ag-2(LH)(2)] with an unsymmetrically coordina
ted third silver(I) ion. The ligand within the complex was found to un
dergo hydrolysis and redox reactions in the gas phase under FD and FAB
conditions.