The structure of epitaxially sputtered single-crystalline Fe/Ni81Fe19(
001) multilayers was studied using X-ray diffraction. As the thickness
of the Fe layers is increased the structure of the Fe layers changes
from vertically expanded fcc (001) to relaxed fcc (001), and finally,
to bcc (011), thus identically replicating the structural behavior fou
nd in thin Fe films on Cu (001) single crystals. Corresponding to the
structural transitions of the Fe layers are changes in the magnetic pr
operties. The relaxed fee phase contains non-magnetic Fe, which can le
ad to antiferromagnetic coupling of the Ni81Fe19 layers across the Fe
layers.