Cf. Fischer et al., SYSTEMATIC STUDIES OF THE 2S(2) S-1(0)-2S3P P-1(1)0 TRANSITION IN THEBE-LIKE SEQUENCE, Journal of physics. B, Atomic molecular and optical physics, 30(5), 1997, pp. 1163-1172
Results from systematic multiconfiguration Hartree-Fock studies of the
2s(2) (1)S2s3p(1)P(o) transition in the Be-like sequence in the range
of Z = 4-10 are reported for several models. The inclusion of core-va
lence correlation is essential for obtaining good agreement in the len
gth and velocity form of the oscillator strength, the agreement improv
ing with Z and reaching one part in 4000 for neon. in the case of Be,
extensive cancellation occurs in the calculation of the dipole matrix
element and correlation in the 1s(2) core already plays a role at the
1% level of accuracy. The orbitals obtained from the core correlation
model were used in a Breit-Pauli calculation mixing P-1,3(o) states. T
he effect on the allowed transition data is included. The present calc
ulations are generally in better agreement with semi-empirical values
predicted from experiment than from experiment itself.