CATALYTIC REACTIONS OF SAMARIUM(II) IODIDE

Authors
Citation
Ej. Corey et Gz. Zheng, CATALYTIC REACTIONS OF SAMARIUM(II) IODIDE, Tetrahedron letters, 38(12), 1997, pp. 2045-2048
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
12
Year of publication
1997
Pages
2045 - 2048
Database
ISI
SICI code
0040-4039(1997)38:12<2045:CROSI>2.0.ZU;2-Y
Abstract
A system for in situ regeneration of SmI2 from SmI3 is described which allows the annulation of ketones to gamma-lactones, the deoxygenation of oxiranes to olefins and radical pi-cyclization to be conducted wit h 10 mole % SmI2. (C) 1997 Elsevier Science Ltd.