DESIGN OF PHOTOAFFINITY REAGENTS FOR LABELING THE AUXIN RECEPTOR IN MAIZE

Authors
KOSEMURA S EMORI H YAMAMURA S ANAI T TOMITA K HASEGAWA K
Citation
S. Kosemura et al., DESIGN OF PHOTOAFFINITY REAGENTS FOR LABELING THE AUXIN RECEPTOR IN MAIZE, Tetrahedron letters, 38(12), 1997, pp. 2125-2128
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
12
Year of publication
1997
Pages
2125 - 2128
Database
ISI
SICI code
0040-4039(1997)38:12<2125:DOPRFL>2.0.ZU;2-U
Abstract
In order to isolate the auxin receptor, we have successfully synthesiz ed two analogues of benzoxazolinones with a trifluoromethyldiazirine g roup as a photoaffinity probe. These compounds inhibited the auxin-ind uced growth of etiolated Avena coleoptile segments. Photolyses of thes e compounds in methanol gave intermolecular O-H insertion products in moderate yields, respectively. (C) 1997 Elsevier Science Ltd.