ALKYLATION OF TRICARBONYL(DIENE)IRON COMPLEXES - MODEL STUDIES FOR THE PREPARATION OF PROTOMYCINOLIDE-IV

Authors
WASICAK JT CRAIG RA HENRY R DASGUPTA B LI HM DONALDSON WA
Citation
Jt. Wasicak et al., ALKYLATION OF TRICARBONYL(DIENE)IRON COMPLEXES - MODEL STUDIES FOR THE PREPARATION OF PROTOMYCINOLIDE-IV, Tetrahedron, 53(12), 1997, pp. 4185-4198
Citations number
51
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
12
Year of publication
1997
Pages
4185 - 4198
Database
ISI
SICI code
0040-4020(1997)53:12<4185:AOTC-M>2.0.ZU;2-0
Abstract
The alkylation of (4,6-heptadien-3-one)- and (methyl 3,5-hexadienoate) Fe(CO)(3) (1 and 2) were examined (0-42% de and 69-92% de respectively ). Optically active (methyl 3,5-hexadienoate)Fe(CO)(3) (-)-2 was prepa red by resolution of the corresponding carboxylic acid complex with al pha-methylbenyzlamine. (C) 1997 Elsevier Science Ltd.