R. Sasai et al., ELECTROOPTICS OF DISPERSED SYSTEMS .6. ELECTRIC BIREFRINGENCE OF NA-MONTMORILLONITE SUSPENDED IN WATER-ETHANOL MIXED-SOLVENT, Chemistry Letters, (3), 1997, pp. 257-258
In order to clarify the effect of ethanol on the electrooptic and hydr
odynamic properties of Na-montmorillonite (Na-M), the transient and st
eady-state electric birefringence (EB) of Na-M was measured in the wat
er-ethanol mixed solvent system at a low particle concentration and at
various ethanol contents. The hydrodynamic size of Na-M was decreased
at ca. 10 vol% in EtOH content. This first EB attempt strongly suppor
ts the notion that the Na-M layers are delaminated by the adsorption o
f EtOH molecules onto the Na-M disk.