Thermal infrared (IR) imaging and spectroscopy of comet Hale-Bopp (C/1
995 O1) during June, August, and September 1996 traced the development
of the dust coma several months before perihelion, Images revealed ni
ghtly variations in the brightness of the inner coma from 1 to 12 June
that were correlated with the appearance of a northward-pointing jet.
The central IR flux increased by a factor of 8 between 1 June and 30
September, and the September data showed IR jets that corresponded to
similar structures that were visible in reflected sunlight at shorter
wavelengths. At all epochs, 8- to 13-micrometer spectra of the central
coma revealed a strong silicate emission feature, including an 11.2-m
icrometer feature indicative of crystalline olivine, even when the com
et was at a heliocentric distance of 4.1 astronomical units.