CONCAVE REAGENTS

Authors
Citation
U. Luning, CONCAVE REAGENTS, Journal of materials chemistry, 7(2), 1997, pp. 175-182
Citations number
68
Categorie Soggetti
Chemistry Physical","Material Science
ISSN journal
09599428
Volume
7
Issue
2
Year of publication
1997
Pages
175 - 182
Database
ISI
SICI code
0959-9428(1997)7:2<175:CR>2.0.ZU;2-Y
Abstract
The concave geometry of enzymes is important for the high selectivity of their reactions. By analogy, the incorporation of standard reagents of organic chemistry into a concave environment gives concave reagent s with a geometry resembling that of a light bulb in a lampshade. Sele ctivity enhancements have been realized in protonations, base catalyse d reactions and metal ion catalysed reactions.